A 0.250 mol sample of a gas occupies 5.60 L at 298 K. Calculate the pressure (kPa). Answer: p = nRT/V = (0.250 mol)(8.314 J mol⁻¹ K⁻¹)(298 K)/(5.60 L) = 111 kPa (≈ 1.1 atm).
Explain why evaporation occurs at any temperature, but boiling does not. Answer: Evaporation only requires a few high‑energy surface molecules to overcome intermolecular forces; boiling requires the vapour pressure of the whole liquid to equal the external pressure.
2. Atoms, Elements & Compounds
Learning Objectives
Recall the structure of an atom, isotopes and ions (AO1).
Explain ionic, covalent and metallic bonding (AO2).
Write correct chemical formulas and balanced equations (AO3).
Key Concepts
Atomic structure – protons (+), neutrons (0), electrons (‑); atomic number = # protons; mass number = protons + neutrons.
Isotopes – same Z, different A; e.g. ¹²C, ¹³C, ¹⁴C.
Ions – gain or loss of electrons; cation (+), anion (‑).
Ionic bonding – transfer of electrons from metal to non‑metal, forming a lattice of oppositely charged ions (e.g. NaCl).
Covalent bonding – sharing of electron pairs between non‑metals (e.g. H₂O, CH₄).
Metallic bonding – delocalised “sea of electrons” around positive metal ions; explains conductivity, malleability.
Formula writing – use subscripts to show the lowest whole‑number ratio of atoms; polyatomic ions retain their internal formula (e.g. Na₂SO₄).
Balancing equations – same number of each type of atom on both sides; total charge conserved.
Practice Questions
Write the formula for calcium nitrate. Answer: Ca(NO₃)₂.