Atoms, Nuclei and Radiation – Cambridge 9702 (A‑Level)
Learning Objective
Describe the composition, mass and charge of the three main types of nuclear radiation (α, β⁻, β⁺ and γ). Write correct decay equations (including neutrinos/antineutrinos), state the relevant conservation laws and recognise the characteristic energy spectra of α‑ and β‑radiations.
1. Nuclear Model & Rutherford Scattering (Syllabus 11.1)
- Rutherford’s α‑scattering experiment (1911) showed that most of the atom is empty space and that a tiny, massive, positively‑charged nucleus (≈ 10⁻¹⁴ m radius) resides at the centre.
- α‑particles (He‑2 nuclei) from a radioactive source were directed at a thin gold foil. Most passed straight through, but a few were deflected at large angles, proving the existence of a concentrated positive charge.
Suggested diagram: a beam of α‑particles incident on a gold foil with some particles scattered at wide angles, indicating a compact nucleus.
2. Nucleon Number (A) and Proton Number (Z)
- A (mass number) = total number of nucleons (protons + neutrons) in the nucleus.
- Z (atomic number) = number of protons; also the charge of the nucleus in units of the elementary charge e.
- Both A and Z are conserved in nuclear reactions (except that A can change by 4 in α‑decay, Z by ±1 in β‑decay, but the total before and after remains the same).
3. Isotopes & Nuclear Notation
An isotope is a nuclide with the same Z (same element) but a different A (different number of neutrons).
| Notation | Isotope | Explanation |
|---|
| \({}^{12}_{6}\!C\) | Carbon‑12 | A = 12, Z = 6 (6 p + 6 n) |
| \({}^{14}_{6}\!C\) | Carbon‑14 | A = 14, Z = 6 (6 p + 8 n) – radioactive |
In a decay the superscript (A) and subscript (Z) change according to the type of radiation emitted, while the element symbol (X) may change when Z changes.
4. Radiation Types – Composition, Mass, Charge & Penetration
| Radiation | Particle / Photon | Composition (nuclear notation) | Mass (relative to 1 u) | Charge (in e) | Energy Spectrum | Typical Shielding / Penetration |
|---|
| α | Helium‑2 nucleus | \({}^{4}_{2}\!He\) (2 p + 2 n) | ≈ 4 u (6.64 × 10⁻²⁷ kg) | +2 e | Discrete (single kinetic energy per isotope) | Stopped by a sheet of paper, a few cm of air or ≈ 0.5 mm Al |
| β⁻ | Electron | e⁻ (no nucleus) | ≈ 5.5 × 10⁻⁴ u (9.11 × 10⁻³¹ kg) | –1 e | Continuous (0 → Emax) | Few mm of aluminium; higher energies need cm of Al |
| β⁺ | Positron (antielectron) | e⁺ (no nucleus) | ≈ 5.5 × 10⁻⁴ u (9.11 × 10⁻³¹ kg) | +1 e | Continuous (0 → Emax) | Few mm of Al; annihilation produces two 511 keV γ‑rays |
| γ | Photon (electromagnetic wave) | — | 0 (no rest mass) | 0 (neutral) | Discrete (energy = nuclear level difference) | Highly penetrating – several cm of lead or metres of concrete |
5. Decay Equations (including neutrinos)
5.1 Alpha Decay
General form
\[
{}^{A}{Z}\!X \;\longrightarrow\; {}^{A-4}{Z-2}\!Y \;+\; {}^{4}_{2}\!He\;(\alpha)
\]
Example (uranium‑238)
\[
{}^{238}{92}\!U \;\longrightarrow\; {}^{234}{90}\!Th \;+\; {}^{4}_{2}\!He
\]
5.2 Beta‑Minus Decay
\[
{}^{A}{Z}\!X \;\longrightarrow\; {}^{A}{Z+1}\!Y \;+\; e^{-} \;+\; \bar{\nu}_{e}
\]
Example (carbon‑14)
\[
{}^{14}{6}\!C \;\longrightarrow\; {}^{14}{7}\!N \;+\; e^{-} \;+\; \bar{\nu}_{e}
\]
5.3 Beta‑Plus Decay (Positron Emission)
\[
{}^{A}{Z}\!X \;\longrightarrow\; {}^{A}{Z-1}\!Y \;+\; e^{+} \;+\; \nu_{e}
\]
Example (fluorine‑18)
\[
{}^{18}{9}\!F \;\longrightarrow\; {}^{18}{8}\!O \;+\; e^{+} \;+\; \nu_{e}
\]
5.4 Electron Capture (alternative to β⁺)
\[
{}^{A}{Z}\!X \;+\; e^{-}{\text{(K or L shell)}} \;\longrightarrow\; {}^{A}{Z-1}\!Y \;+\; \nu{e}
\]
Example (beryllium‑7)
\[
{}^{7}{4}\!Be \;+\; e^{-} \;\longrightarrow\; {}^{7}{3}\!Li \;+\; \nu_{e}
\]
5.5 Gamma Emission
\[
{}^{A}{Z}\!X^{*} \;\longrightarrow\; {}^{A}{Z}\!X \;+\; \gamma
\]
\({}^{A}_{Z}\!X^{*}\) denotes an excited nucleus that de‑excites by emitting a photon.
6. Conservation Checks (quick reference)
- Mass number (A): unchanged in α, β⁻, β⁺, electron capture and γ decays (the emitted particle’s A is accounted for).
- Charge (Z): conserved when the charge of the emitted particle is included (+2 for α, –1 for β⁻, +1 for β⁺, 0 for γ).
- Energy: total decay energy is shared between kinetic energy of the emitted particles and (anti)neutrinos; for γ‑rays it appears as photon energy.
- Linear momentum: conserved; in two‑body α‑decay the daughter nucleus recoils opposite the α‑particle.
7. Energy Spectra – Why They Differ
- α‑particles: Two‑body decay → fixed Q‑value → α‑particle emerges with a single kinetic energy (discrete line).
- β‑particles (β⁻ and β⁺): Three‑body decay (daughter + β + (anti)neutrino) → kinetic energy is shared continuously → continuous spectrum from 0 up to a maximum \(E_{\max}\).
- γ‑rays: Emitted when an excited nucleus drops to a lower energy level → photon energy equals the exact difference between the two nuclear levels (discrete lines).
8. Compact Summary Table
| Radiation | Particle / Photon | Mass (kg) | Charge (e) | Energy Spectrum | Typical Shielding |
|---|
| α | He‑2 nucleus | 6.64 × 10⁻²⁷ | +2 | Discrete | Paper, 0.5 mm Al |
| β⁻ | Electron | 9.11 × 10⁻³¹ | –1 | Continuous | Few mm Al |
| β⁺ | Positron | 9.11 × 10⁻³¹ | +1 | Continuous | Few mm Al (plus 511 keV γ‑rays) |
| γ | Photon | 0 | 0 | Discrete | Several cm Pb or m concrete |
9. Common Misconceptions
- “All radiation is equally dangerous.” – α particles cannot penetrate skin; they are hazardous only if ingested or inhaled. β particles can cause skin burns, while γ rays are the most penetrating and require dense shielding.
- “β‑radiation is just electrons.” – β⁻ are electrons; β⁺ are positrons (the electron’s antimatter counterpart) and annihilate with electrons, producing 511 keV γ‑rays.
- “γ‑rays are particles.” – They are high‑energy photons, i.e., quanta of electromagnetic radiation, not matter particles.
- “Neutrinos carry charge.” – Neutrinos and antineutrinos are electrically neutral; they escape the nucleus carrying away energy and angular momentum.
10. Key Equations for the Syllabus
- Mass–energy equivalence: \(E = mc^{2}\)
- Charge conservation: \(\displaystyle\sum Q{\text{initial}} = \sum Q{\text{final}}\)
- Energy balance in β‑decay (three‑body): \(Q = T{\beta} + T{\nu} + (m{\text{daughter}}-m{\text{parent}})c^{2}\)
11. Suggested Classroom Diagram
A single illustration showing a nucleus emitting:
- (i) an α‑particle (large, +2 e, short arrow, labelled “α”),
- (ii) a β⁻ electron (small, –1 e, longer arrow, labelled “β⁻”),
- (iii) a β⁺ positron (small, +1 e, labelled “β⁺”),
- (iv) a γ‑photon (wavy line, labelled “γ”).
Next to each arrow indicate relative size, charge symbol, typical shielding material and, for β⁺, the annihilation γ‑rays.