understand that the charge on charge carriers is quantised

1 Electric Current

1.1 Definition and basic equation

  • Electric current is the rate at which electric charge passes a given point in a circuit.
  • Mathematically

    \[

    I=\frac{\Delta Q}{\Delta t}\qquad\text{(ampere, A)}

    \]

    where \(\Delta Q\) is the charge transferred (C) in the time interval \(\Delta t\) (s).

  • Re‑arranging gives the useful relation

    \[

    Q = I\,t

    \]

    which allows us to calculate the total charge that has passed in a time \(t\).

1.2 Charge carriers

The particles that actually move when a current flows are called charge carriers. Their nature depends on the material:

MaterialCharge carriersTypical charge \(q\)
MetalsFree electrons\(-e\)
ElectrolytesIons (cations + anions)\(\pm e\) (or multiples)
SemiconductorsElectrons and holes\(-e\) (electron), \(+e\) (hole)

1.3 Microscopic description of current

  • Current density

    \[

    J = \frac{I}{A}\qquad\text{(A m\(^{-2}\))}

    \]

    where \(A\) is the cross‑sectional area of the conductor.

  • Microscopic expression (useful for metals and doped semiconductors)

    \[

    I = A\,n\,v\,q

    \]

    where

    \(A\) = cross‑sectional area (m\(^2\))

    \(n\) = number of charge carriers per unit volume (m\(^{-3}\))

    \(v\) = drift speed of the carriers (m s\(^{-1}\))

    \(q\) = charge on each carrier (C, usually \(\pm e\)).

Example – current in a copper wire

Given: copper wire of length 0.50 m, cross‑sectional area \(A = 1.0\times10^{-6}\,\text{m}^2\), free‑electron density \(n = 8.5\times10^{28}\,\text{m}^{-3}\), drift speed \(v = 2.0\times10^{-4}\,\text{m s}^{-1}\).

\[

I = A n v e = (1.0\times10^{-6})(8.5\times10^{28})(2.0\times10^{-4})(1.602\times10^{-19})

\approx 2.7\ \text{A}

\]

2 Potential Difference & Electrical Power

2.1 Potential difference (voltage)

Potential difference is the energy transferred per unit charge:

\[

V = \frac{W}{Q}\qquad\text{(volt, V)}

\]

where \(W\) is the work (or energy) done on the charge \(Q\).

2.2 Electrical power

Power is the rate at which electrical energy is transferred:

\[

P = \frac{W}{t}=VI\qquad\text{(watt, W)}

\]

Using Ohm’s law (\(V = IR\)) we obtain two additional useful forms:

\[

P = I^{2}R\qquad\text{and}\qquad P = \frac{V^{2}}{R}

\]

Example – a 12 V lamp drawing 2 A

\[

P = VI = (12\ \text{V})(2\ \text{A}) = 24\ \text{W}

\]

3 Resistance, Resistivity & Ohm’s Law

3.1 Macroscopic resistance

  • Resistance \(R\) opposes the flow of charge and is defined by Ohm’s law:

    \[

    V = I R\qquad\text{(Ω = V A\(^{-1}\))}

    \]

  • For a uniform conductor of length \(L\) and cross‑sectional area \(A\):

    \[

    R = \rho\,\frac{L}{A}

    \]

    where \(\rho\) is the material’s resistivity (Ω m).

3.2 I‑V characteristics (required by the syllabus)

ComponentI‑V shapeKey features
Ohmic conductor (e.g., copper wire)Straight line through the originConstant resistance; \(V\propto I\)
Semiconductor diodeVery low current until a “turn‑on” voltage, then steep riseNon‑linear; conducts only above threshold
Filament lampCurve that becomes steeper with increasing \(I\)Resistance rises with temperature
LDR (light‑dependent resistor)Flatter slope in light, steeper in darkResistance decreases with light intensity
Thermistor (NTC)Curve bending downwards as \(I\) increasesResistance falls as temperature rises

Worked example – resistance of a nichrome wire

Length \(L = 0.30\ \text{m}\), cross‑section \(A = 2.0\times10^{-6}\ \text{m}^2\), resistivity \(\rho = 1.10\times10^{-6}\ \Omega\text{m}\).

\[

R = \rho\frac{L}{A}= (1.10\times10^{-6})\frac{0.30}{2.0\times10^{-6}}

= 0.165\ \Omega

\]

4 Quantisation of Charge

4.1 Fundamental statement

All observable electric charge occurs in integer multiples of the elementary charge \(e\):

\[

q = n\,e\qquad n = \pm1,\pm2,\pm3,\dots

\]

\[

e = 1.602\,\times10^{-19}\ \text{C}

\]

4.2 Experimental evidence (syllabus requirement)

  1. Millikan oil‑drop experiment – Direct measurement of individual droplet charges showed they are integer multiples of \(e\).
  2. Photoelectric effect – Each emitted electron carries a charge of exactly \(-e\).
  3. Charge balance in chemical reactions – Ions exchange whole numbers of elementary charges.

4.3 Typical charge carriers

CarrierSymbolCharge \(q\)Typical medium
Electron\(e^{-}\)\(-e\)Metals, semiconductors
Proton\(p^{+}\)\(+e\)Atomic nuclei
Alpha particle\(\alpha^{2+}\)\(+2e\)Radioactive decay
Sodium ion\(\text{Na}^{+}\)\(+e\)Electrolytes
Chloride ion\(\text{Cl}^{-}\)\(-e\)Electrolytes

4.4 Linking quantised charge to macroscopic current

The number of charge carriers crossing a cross‑section each second is

\[

N = \frac{I}{e}

\]

Thus a current of \(1\ \text{A}\) corresponds to

\[

N = \frac{1\ \text{C s}^{-1}}{1.602\times10^{-19}\ \text{C}}

\approx 6.24\times10^{18}\ \text{carriers s}^{-1}

\]

5 DC Circuits (AS‑Level requirement)

5.1 Circuit symbols (syllabus §6)

ComponentSymbol (hand‑drawn)
Battery (ideal emf)Battery symbol
ResistorError loading subjects.

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