Describe practical methods for investigating the rate of a reaction including change in mass of a reactant or a product and the formation of a gas

Chemical Reactions – Rate of Reaction

What is a “Rate of Reaction”?

It tells us how fast a reaction proceeds. Think of it as the speed of a race: the faster the runners, the quicker the finish line is crossed. In chemistry, we measure how fast reactants disappear or products appear.

Practical Methods to Measure Reaction Rate

  • Change in mass of a reactant or product
  • Formation of a gas (volume or pressure change)
  • Colour change (spectrophotometry)
  • Temperature change (calorimetry)

Exam Tip

When a question asks for a “practical method,” list at least two techniques and explain how they give a quantitative measure of the rate. Use the word “rate” and show the relationship to time.

1. Change in Mass of a Reactant or Product

Imagine you’re baking a cake. The batter (reactant) loses mass as it turns into cake (product) and releases water vapor. In a lab, we can weigh the reactant before and after the reaction.

  1. Weigh the reactant \$m_{\text{initial}}\$ accurately.
  2. Carry out the reaction in a sealed container.
  3. After a fixed time, weigh the remaining reactant or the product \$m_{\text{final}}\$.
  4. Calculate the mass change: \$\Delta m = m{\text{initial}} - m{\text{final}}\$.
  5. Divide by the time interval to get the rate: \$\text{Rate} = \frac{\Delta m}{\Delta t}\$.

⚠️ Remember: The container must be airtight to prevent loss of mass through gases. If gases escape, the measured mass change will be inaccurate.

Exam Tip

When asked to calculate the rate from a mass change, show the equation and plug in the numbers. Highlight that the rate is expressed in g s⁻¹ or kg min⁻¹ depending on the units given.

2. Formation of a Gas

Think of blowing up a balloon. The amount of air (gas) inside tells you how much gas has been produced. In a reaction, we can measure the volume or pressure of the gas produced.

  1. Set up a reaction in a gas syringe or a sealed container with a flexible bulb.
  2. Record the initial volume or pressure of the gas (usually 0 if the container is empty).
  3. Allow the reaction to proceed for a known time.
  4. Measure the new volume \$V{\text{final}}\$ or pressure \$P{\text{final}}\$.
  5. Calculate the change: \$\Delta V = V{\text{final}} - V{\text{initial}}\$ or \$\Delta P = P{\text{final}} - P{\text{initial}}\$.
  6. Rate = \$\frac{\Delta V}{\Delta t}\$ or \$\frac{\Delta P}{\Delta t}\$.

📏 Analogy: If you’re filling a bathtub, the rate at which the water level rises is like the rate of gas formation.

Exam Tip

When a question involves gas volume, use the ideal gas law if temperature and pressure are given: \$PV = nRT\$. Show how to convert moles of gas to volume and then to a rate.

Sample Data Table

Time (s)Mass of Reactant (g)Gas Volume (mL)
010.000
309.7015
609.4030

From this data, you can calculate the rate of mass loss: \$\frac{10.00-9.70}{30} = 0.010\,\text{g s}^{-1}\$ and the rate of gas production: \$\frac{15-0}{30} = 0.5\,\text{mL s}^{-1}\$.

Final Exam Tip

Always state the units of your final answer. If the question asks for the “rate of reaction,” give both the numerical value and the unit, e.g., 0.010 g s⁻¹ or 0.5 mL s⁻¹. Show the calculation steps clearly; examiners look for a logical flow.