State that a structural formula is an unambiguous description of the way the atoms in a molecule are arranged, including $mathrm{CH}_2=mathrm{CH}_2$, $mathrm{CH}_3 mathrm{CH}_2 mathrm{OH}, mathrm{CH}_3 mathrm{COOCH}_3$

Organic Chemistry – Formulae, Functional Groups & Terminology

What is a Structural Formula?

A structural formula is like a blueprint that shows exactly how every atom is connected in a molecule. It tells you which atoms are bonded, the type of bonds (single, double, triple), and the arrangement of atoms in space. Think of it as the road map of a city – it shows all the streets (bonds) and buildings (atoms) so you can navigate from one point to another without guessing. 🚗🏙️

Examples of Structural Formulae

  • Alkene (ethylene): \$ \mathrm{CH2=CH2} \$ – two carbon atoms double‑bonded, each with two hydrogens.
  • Alcohol (ethanol): \$ \mathrm{CH3CH2OH} \$ – a chain of two carbons with an –OH group on the second carbon.
  • Ester (methyl acetate): \$ \mathrm{CH3COOCH3} \$ – a carbonyl group (C=O) linked to an –O–CH₃ group.

Functional Groups – Quick Reference

GroupKey FeatureExample
AlkaneAll single C–C bonds\$ \mathrm{CH_4} \$ (methane)
AlkeneOne C=C double bond\$ \mathrm{CH2=CH2} \$ (ethylene)
AlkyneOne C≡C triple bond\$ \mathrm{HC≡CH} \$ (acetylene)
Alcohol–OH group attached to C\$ \mathrm{CH3CH2OH} \$ (ethanol)
Ester–COO– linkage\$ \mathrm{CH3COOCH3} \$ (methyl acetate)

Terminology to Know

  1. Atom – the basic building block (C, H, O, N, etc.).
  2. Bond – connection between two atoms (single, double, triple).
  3. Functional Group – a specific arrangement of atoms that gives a molecule its characteristic properties.
  4. Isomer – compounds with the same molecular formula but different structural arrangements.
  5. Chirality – a molecule that cannot be superimposed on its mirror image (like left and right hands).

Exam Tips 📚

  • Always label every atom in a structural formula – missing a hydrogen can change the answer.
  • Show bond order clearly: use "=" for double bonds and "≡" for triple bonds.
  • When drawing a new molecule, start with the backbone (main chain) before adding side groups.
  • Practice naming by identifying the longest chain and the highest‑priority functional group first.
  • Use colour coding in your notes: e.g., blue for carbons, red for heteroatoms, green for functional groups.