Define a reducing agent as a substance that reduces another substance and is itself oxidised

Chemical Reactions – Redox

What is a Reducing Agent?

A reducing agent (or reductant) is a substance that donates electrons to another substance, causing that other substance to be reduced (gain electrons). At the same time, the reducing agent itself is oxidised (loses electrons).

Think of it like a generous friend who gives away their candies (electrons) to help another friend get a candy (be reduced). The generous friend ends up with fewer candies (is oxidised).

In chemical notation: \$e^-\$ is the electron that is transferred.

Common Reducing Agents

Reducing AgentOxidised FormTypical Reaction
Na (sodium)Na⁺\$2\text{Na} + 2\text{H}2\text{O} \rightarrow 2\text{NaOH} + \text{H}2\$
H₂ (hydrogen gas)H⁺\$2\text{H}2 + \text{O}2 \rightarrow 2\text{H}_2\text{O}\$
C (carbon)CO₂\$C + \text{O}2 \rightarrow \text{CO}2\$

How to Spot the Reducing Agent

  1. Identify which species is gaining electrons (becoming reduced).
  2. That species is the oxidised form of the reducing agent.
  3. The substance that loses electrons (becomes oxidised) is the reducing agent.

🔁 Remember: Reducing agent = electron donor = oxidised in the reaction.

Exam Tip 💡

When you see a redox reaction, look for the species that changes its oxidation state from lower to higher. That species is the reducing agent. Write the oxidation numbers before and after to confirm.

Use the mnemonic “LEO the lion says GER”:

  • Lose electrons = Exchange = Oxidation
  • Gain electrons = Exchange = Reduction

🧪 Practise balancing a few redox equations to get comfortable.

Quick Summary

  • A reducing agent donates electrons and is oxidised.
  • The species that gains electrons is reduced.
  • Check oxidation numbers to identify the reducing agent.
  • Remember the mnemonic “LEO the lion says GER”.