State that an endothermic reaction takes in thermal energy from the surroundings leading to a decrease in the temperature of the surroundings

Chemical Energetics: Exothermic & Endothermic Reactions

Key Concept

An endothermic reaction absorbs thermal energy from its surroundings. This causes the surroundings to feel cooler, just like when you feel a chill after a cold shower! ❄️

Analogy: The Ice Cream Scoop

Think of an endothermic reaction as a scoop of ice cream melting in your hand. The ice cream takes heat from your hand (the surroundings) to melt, so your hand feels colder. The reaction’s enthalpy change is \$ΔH > 0\$.

Analogy: The Campfire

An exothermic reaction is like a campfire: it releases heat into the surroundings, making the air feel warm. The reaction’s enthalpy change is \$ΔH < 0\$. 🔥

Comparing Exothermic & Endothermic

FeatureExothermicEndothermic
Heat FlowOut of the reactionInto the reaction
ΔH\$ΔH < 0\$\$ΔH > 0\$
Surroundings TemperatureIncreasesDecreases
Common ExampleCombustion of woodMelting of ice

Exam Tip

When you see a reaction that absorbs heat (e.g., dissolving ammonium nitrate in water), remember: \$ΔH > 0\$ and the surroundings feel cooler. Use the word “endothermic” to label it in your answer. 📘

Quick Check

  1. Identify the direction of heat flow.
  2. Determine the sign of \$ΔH\$.
  3. Predict whether the surroundings will feel warmer or cooler.