A photon is a packet of light energy. Its energy depends only on its frequency (\$f\$) and is given by Planck’s relation:
\$E_{photon}=hf\$
where \$h=6.63\times10^{-34}\text{ J·s}\$ is Planck’s constant.
When a photon strikes a metal surface, it can eject an electron if its energy exceeds the work function (\$\Phi\$) of the metal. The excess energy becomes the kinetic energy of the emitted electron.
The conservation of energy for the photoelectric process is written as:
\$hf = \Phi + \frac{1}{2}mv_{max}^2\$
| Symbol | Meaning | Typical Value / Units |
|---|---|---|
| \$h\$ | Planck’s constant | \$6.63\times10^{-34}\text{ J·s}\$ |
| \$f\$ | Photon frequency | Hz (s\$^{-1}\$) |
| \$\Phi\$ | Work function of metal | eV (convert to J: \$1\text{ eV}=1.60\times10^{-19}\text{ J}\$) |
| \$m\$ | Electron mass | \$9.11\times10^{-31}\text{ kg}\$ |
| \$v_{max}\$ | Maximum electron speed | m/s |
A photon of frequency \$f = 1.0\times10^{15}\text{ Hz}\$ strikes a sodium surface whose work function is \$\Phi = 2.3\text{ eV}\$. Calculate the maximum speed of the emitted electron.
\$\Phi = 2.3\text{ eV}\times1.60\times10^{-19}\frac{\text{J}}{\text{eV}} = 3.68\times10^{-19}\text{ J}\$
\$E_{photon}=hf = (6.63\times10^{-34})(1.0\times10^{15}) = 6.63\times10^{-19}\text{ J}\$
\$K{max}=E{photon}-\Phi = 6.63\times10^{-19} - 3.68\times10^{-19}=2.95\times10^{-19}\text{ J}\$
\$v{max}=\sqrt{\frac{2K{max}}{m}} = \sqrt{\frac{2(2.95\times10^{-19})}{9.11\times10^{-31}}}\$
\$v_{max}\approx \sqrt{6.48\times10^{11}} \approx 8.0\times10^{5}\text{ m/s}\$
Thus the fastest electron leaves the sodium surface with a speed of about \$8.0\times10^{5}\text{ m/s}\$.
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