Describe the manufacture of ethanol by: (a) fermentation of aqueous glucose at $25-35^{circ} mathrm{C}$ in the presence of yeast and in the absence of oxygen (b) catalytic addition of steam to ethene at $300^{circ} mathrm{C}$ and $6000 mathrm{kPa} /

Manufacturing Ethanol: Two Paths 🚀

1️⃣ Fermentation of Glucose (Biological Route)

Think of fermentation like baking bread, but instead of dough, we use a sugary solution of glucose. Yeast, the tiny bread‑making microbes, eat the glucose and, in a low‑oxygen (anaerobic) environment, convert it into ethanol and carbon dioxide.

  1. Prepare an aqueous solution of glucose: \$C6H{12}O_6\$.
  2. Add a pinch of yeast (usually Saccharomyces cerevisiae).
  3. Keep the mixture warm between \$25\$\$35^{\circ}\text{C}\$ (room temperature to a mild kitchen heat).
  4. Seal the container to keep oxygen out – imagine a closed jar of bread dough.
  5. After a few days, the yeast will have produced ethanol and CO₂:

\$C6H{12}O6 \;\xrightarrow{\text{yeast, 25–35 °C, no O₂}}\; 2\,C2H5OH + 2\,CO2\$

🍺 Result: Ethanol (the alcohol in beer) and CO₂ (the bubbles).

2️⃣ Catalytic Addition of Steam to Ethene (Chemical Route)

Imagine a high‑pressure kitchen where a gas (ethene) is given a friendly splash of water (steam) under a strong acid “chef” (catalyst). The acid helps the water molecule attach to the ethene, forming ethanol.

  1. Feed ethene gas (\$C2H4\$) into a reactor.
  2. Add steam (\$H_2O\$) and pressurise to about \$6000\ \text{kPa}\$ (~\$60\$ atm).
  3. Heat the mixture to \$300^{\circ}\text{C}\$.
  4. Introduce an acid catalyst (often sulfuric acid or a solid acid like zeolite).
  5. The reaction proceeds:

\$C2H4 + H2O \;\xrightarrow{H^+}\; C2H_5OH\$

⚙️ Result: Ethanol produced on an industrial scale, ready for fuel or chemical use.

Comparison of the Two Methods

FeatureFermentationSteam‑Addition
Energy InputLow (ambient heat)High (300 °C, 60 atm)
Raw MaterialsGlucose (sugar)Ethene + Steam
ScaleSmall‑scale, lab or craftLarge‑scale, industrial
Environmental ImpactBiodegradable, low emissionsRequires energy, acid handling

Key Takeaways for 15‑Year‑Olds

  • Fermentation is like baking bread: yeast eats sugar and makes alcohol.
  • The steam‑addition method is like a high‑pressure kitchen where a gas gets a splash of water under a strong acid “chef”.
  • Both routes give the same product (ethanol) but use different ingredients and conditions.
  • Understanding these processes helps you see how everyday products (like fuels or drinks) are made from simple molecules.

🔬 Keep exploring – chemistry turns ordinary things into amazing transformations!