2.2.1 Thermal Expansion of Solids, Liquids and Gases
What is Thermal Expansion?
When the temperature of a material changes, its particles move more vigorously and the average separation between them changes.
This results in a change of size – an increase when heated and a decrease when cooled.
Mathematical Description
For small temperature changes the expansion can be approximated by linear relationships:
Linear expansion of a solid: \$\Delta L = \alpha L_0 \Delta T\$
Area expansion of a thin plate: \$\Delta A = 2\alpha A_0 \Delta T\$
Volume expansion of a solid or liquid: \$\Delta V = \beta V_0 \Delta T\$ where \$\beta \approx 3\alpha\$ for isotropic solids.
For an ideal gas the volume change with temperature at constant pressure is given by Charles’s law: \$\frac{V}{T}= \text{constant}\$ or \$\frac{V2}{V1}= \frac{T2}{T1}\$ (temperatures in kelvin).
Coefficients of Thermal Expansion
Typical coefficients (α for linear, β for volume) for common materials are shown below.
Material
Linear coefficient, α (×10⁻⁶ °C⁻¹)
Volume coefficient, β (×10⁻⁶ °C⁻¹)
Aluminium
23
69
Steel (carbon)
12
36
Copper
17
51
Glass (window)
9
27
Water (liquid, 0‑4 °C)
–
–
Air (at 1 atm)
–
≈ 3400
Everyday Applications
Applications Involving Solids
Expansion joints in bridges and railway tracks: Small gaps allow the structure to expand without buckling.
Thermostats (bimetallic strips): Two metals with different α are bonded; heating causes the strip to bend and operate a switch.
Fit of metal lids on glass jars: The lid is heated to expand, placed on the jar, and then cools to create a tight seal.
Applications Involving Liquids
Thermometers (mercury or alcohol): The liquid expands linearly with temperature, moving up a calibrated tube.
Hot‑water heating systems: Expansion tanks accommodate the increase in water volume when heated.
Fuel‑level gauges in cars: The fuel expands with temperature; the gauge is calibrated to account for this.
Applications Involving Gases
Hot‑air balloons: Heating the air inside reduces its density, providing lift.
Internal combustion engines: The rapid expansion of gases pushes pistons, producing work.
Air‑conditioners and refrigerators: Compression and expansion of refrigerant gases absorb and release heat.
Consequences of Thermal Expansion
Structural damage: If expansion is restrained, compressive stresses develop, leading to cracks (e.g., cracked railway tracks in summer).
Misalignment of precision instruments: Optical benches, laser interferometers, and measuring devices must be mounted on low‑expansion materials (e.g., Invar) to maintain accuracy.
Failure of sealed containers: Pressure build‑up in a closed vessel can cause rupture unless a safety valve or expansion space is provided.
Changes in volume of liquids and gases affect flow rates: Pipelines transporting oil or gas need temperature compensation to maintain constant flow.
Design Strategies to Manage Expansion
Use materials with low coefficients of expansion (e.g., Invar, fused silica) for precision parts.
Incorporate expansion joints, sliding bearings, or flexible couplings in large structures.
Provide clearance gaps in assemblies (e.g., between rails, bridge decks, and supports).
Install pressure relief valves on sealed containers.
Summary Table – Key Points
Category
Typical Example
Result of Heating
Practical Measure
Solid – Metal bridge
Steel girder
Length increases → possible buckling
Expansion joints at regular intervals
Solid – Bimetallic thermostat
Nickel‑chrome & steel strip
Differential bending
Operates a switch at set temperature
Liquid – Thermometer
Mercury column
Column rises with temperature
Calibrated scale on glass tube
Gas – Hot‑air balloon
Heated air inside envelope
Volume increases, density decreases
Control burner to adjust lift
Suggested diagram: Expansion joint in a railway track showing the gap that allows the rails to expand in summer without buckling.
Suggested diagram: Bimetallic strip bending when heated, illustrating the principle of a thermostat.
Suggested diagram: Mercury thermometer with labelled scale and bulb.