Recall and use the equation \$n = \frac{1}{\sin c}\$ where n is the refractive index of a medium and c is the critical angle for total internal reflection.
Key Concepts
Refraction: The change in direction of a light ray when it passes from one transparent medium to another with a different optical density.
Refractive Index (n): A dimensionless number that describes how fast light travels in a medium compared to vacuum. \$n = \frac{c0}{v}\$ where \$c0\$ is the speed of light in vacuum and \$v\$ is the speed in the medium.
Snell’s Law: Relates the angles of incidence (\$i\$) and refraction (\$r\$) to the refractive indices of the two media. \$n1 \sin i = n2 \sin r\$
Critical Angle (c): The angle of incidence in the denser medium for which the angle of refraction is \$90^{\circ}\$. Beyond this angle total internal reflection occurs.
Equation for Critical Angle: Rearranging Snell’s law for \$r = 90^{\circ}\$ gives \$\sin c = \frac{n2}{n1}\$ for \$n1 > n2\$. Solving for \$n1\$ yields the target equation \$n1 = \frac{1}{\sin c}\$ when the second medium is air (\$n_2 \approx 1\$).
Derivation of \$n = \frac{1}{\sin c}\$
Start with Snell’s law: \$n1 \sin i = n2 \sin r\$
For the critical condition, the refracted ray grazes the interface, so \$r = 90^{\circ}\$ and \$\sin r = 1\$.
Replace \$i\$ with the critical angle \$c\$: \$n1 \sin c = n2\$
If the second medium is air, \$n2 \approx 1\$, giving \$n1 = \frac{1}{\sin c}\$
Typical Refractive Indices
Medium
Refractive Index (n)
Air (standard conditions)
1.00
Water
1.33
Glass (crown)
1.52
Glass (flint)
1.62
Diamond
2.42
Worked Example
Question: Light travelling in glass (n = 1.52) strikes the glass‑air interface. Calculate the critical angle \$c\$ for total internal reflection.
Use the critical‑angle form of Snell’s law: \$\sin c = \frac{n{\text{air}}}{n{\text{glass}}} = \frac{1.00}{1.52}\$
Calculate: \$\sin c = 0.658\$
Find \$c\$ using the inverse sine: \$c = \sin^{-1}(0.658) \approx 41.1^{\circ}\$
Therefore, any incident angle greater than \$41.1^{\circ}\$ will result in total internal reflection.
Practice Questions
Given a critical angle of \$48^{\circ}\$ for a liquid, determine its refractive index using \$n = \frac{1}{\sin c}\$.
A ray of light passes from water into glass. If the angle of incidence in water is \$30^{\circ}\$, calculate the angle of refraction in glass (use \$n{\text{water}} = 1.33\$, \$n{\text{glass}} = 1.52\$).
Explain why a diamond sparkles more than glass, referring to the values of \$n\$ and the resulting critical angles.
Common Mistakes to Avoid
Confusing the critical angle with the angle of incidence that produces the maximum refraction; the critical angle is specific to total internal reflection.
Using the equation \$n = \frac{1}{\sin c}\$ for a situation where the second medium is not air; in such cases the full Snell’s law must be applied.
Forgetting to convert degrees to radians only when using a calculator set to radian mode.
Suggested diagram: Ray diagram showing incident ray, refracted ray, normal, and the critical angle at a glass‑air interface.